Nonoxidative synthesis of dimethoxymethane by gas‐phase methanol dehydrogenation over bifunctional copper catalysts

Selective oxidation of methanol to dimethoxymethane over bifunctional VO(x)/TS-1 catalysts.

This communication describes the design of bifunctional VO(x)/TS-1 catalysts with enhanced redox and acidic character via doping SO(4)(2-) and PO(4)(3-) for selective oxidation of methanol to dimethoxymethane. Redox sites enable the production of formaldehyde, while acidic sites favor the condensation of formaldehyde to DMM.

Novel Porous Iron Molybdate Catalysts for Synthesis of Dimethoxymethane from Methanol: Metal Organic Frameworks as Precursors

As a novel performance, methanol gas conversion to dimethoxymethane (DMM) in one-step based on Fe-Mo-O (iron molybdate mixed oxides) catalysts with high surface area fabricated by metal organic frameworks (MOFs) precursors was improved. For this approach, at first, Fe(III) precursors (iron (III) 1,3,5-benzenetricarboxylate (MIL-100 (Fe) and iron terephthalate (MOF-...

Dehydrogenation by Heterogeneous Catalysts

Methanol from synthesis gas over bimetallic FePd catalysts

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Bifunctional anode catalysts for direct methanol fuel cells

Using the binding energy of OH* and CO* on close-packed surfaces as reactivity descriptors, we screen bulk and surface alloy catalysts for methanol electro-oxidation activity. Using these two descriptors, we illustrate that a good methanol electro-oxidation catalyst must have three key properties: (1) the ability to activate methanol, (2) the ability to activate water, and (3) the ability to re...